M.PIZZICHINI; ENEA – innovation Area, processes and materials department; C.R.E. Casaccia, Roma, Italia |
INTRODUCTION |
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Agroindustrial processes generally involve the transformation of natural foodstuff into useful, non perishable, commercial products. |
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Recent developments in processing technologies, packaging and materials have made possible the development of a whole new food manufacturing industry capable of satisfying the modern trends of human food. |
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As a result, a new food service industry has emerged, supplied by food manufactures with high-quality, especially developed products, packaged in large container, refrigerated, thermally processed or frozen.
In developing countries food must be available and accessible to every person in nutritious, safe and appetising forms. This means that every consideration must be given to the entire food chain, from production to processing, distribution, consumption, and biological utilization.
The application of innovative techniques such as Membrane Technology (MT) in food transformation processes represents a real opportunity to increase and quality the productivity and reduce the environment pollution of farms. The commercial application of MT in food processing industry includes concentration of oil emulsions, blood treatment for proteins recovery, clarification of wine, concentration of fruit juices and treatment of a variety of food processing waste stream.
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In general, MT’s are applied in different unit operations: concentration, purification, clarification, recovery and upgrading of products.
These operations allow to increase the product quality (taste, aroma, apperance,…), the recovery of process byproducts and a high reduction of the process energy consumption. In addition, MT permit a strong reduction of chemicals used for clarification or flocculation of raw natural compounds such as wine, vinegar, beer, fruit juices, coffee, tea, etc.
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MEMBRANE TECHNOLOGY |
Membrane processes such as cross-flow MF, UF and RO, all pressure driven membrane process, have been intensively exploited in the food industry. In this field many products such as juice, milk require removal of large quantities of water to concentrate the products for more efficient packaging or shipping. |
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Table 1. Example of the use of membranes in the food and beverage industries. From Jone (1987) |
Food industry
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Application area |
Membrane processes
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Milk |
Concentration of whole milk and skim milk |
RO, UF |
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Concentration of chesse whey |
RO |
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Fractionation of whole milk or cheese whey |
RO |
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Separation of inhibitors of micro-organism growth for fermentation |
UF |
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Recovery of whey protein from wastes |
UF |
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Hydrolysis of lactose for low lactose milk |
ENZYME |
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Removal of casein, fats and lactose from whey |
MF, RO |
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Demineralisation of whey |
ED |
Fruit juice and vegetable juice |
Fractionation and clarification of apple, vegetable and citrus juices |
MF, UF |
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De-acidification of juices |
UF |
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Concentration of fruit juice |
RO |
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Sterilization of juice prior to bottling of fermentation |
MF, UF |
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Color modification |
UF |
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Recovery of pectin from wastewater of orange juice canning |
UF, RO |
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Recovery of wine or juice from lees |
MF |
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Sterilisation of juice prior to fermentation (controlled) |
MF |
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Clarification and sterilization after fermentation |
UF |
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De alcoholisation |
RO |
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Recovery of reuse water |
UF, RO |
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Vinegar clarification |
MF, UF |
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Molasses – removal of heavy sugars and color, separation of sucrose and hexoses |
RO |
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Desalination of molasses |
RO, ED, CD |
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Cane juice concentration |
RO |
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Sugar waste recovery |
RO |
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Extracts, concentration |
RO |
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Decaffeination |
RO |
Meat stocks, soups, jams, jellies |
Concentration |
RO, UF |
Protein process |
Concentration of egg-white |
UF, RO |
Soy protein concentration |
UF |
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Separation of emulsifiers from enzyme treated soybean extract |
UF |
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Separation of color and salts from hydrolysed vegetable protein |
UF, RO |
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Removal of odour from soybean milk |
UF, RO |
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Clarification of raw and heat treated soy sause |
MF |
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Recovery of protein from wastewater from ham and other food processing operations |
UF, RO |
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Whole egg concentration |
UF |
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Concentration of rennet |
UF, RO |
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Gelation dehydration (concentration) |
UF |
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A substaintial difference between MT and the conventional filtration (dead-end filtration) regards the operation mode, as schematized in Figure 1. In the same figure the morphology of microfiltration membranes are reported.
In MT, the membrane module is operated in a continuously self-cleaning mode, with solutes and solids swept away by the concentrate stream which is running parallel to the membrane surface, hence the term “cross flow” or tangential filtration. In MT the concentrate stream, retained by membrane, can be recirculated through the module in order to obtain the desired concentration ration (VRC). This parameter is given by the ratio between feed volume and final concentrate volume.
Contrary to the distillation process, in MT the separation takes place in isothermal conditions without phase transition, with the opportunity for reusing both concentrate and permeate streams. This permits an energy saving and a low environmental impact, because no byproduct are generated during the seperation process.
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